Thứ Năm, 28 tháng 6, 2018

Waching daily Jun 28 2018

Not sure if you're in the right or wrong relationship?

Keep watching so we can get you clear and I'll tell you what to do about it

Welcome to Power Love TV, my name is Michelle Baxo and for the best advice for women on

falling in love without compromising yourself, subscribe to my channel and hit the bell so

you're notified of our new videos every week.

Let me guess, your mind won't shut up.

You have this nagging thought that maybe this relationship isn't THE ONE after all.

I've been there myself and I do this professionally so let's get you clear, shall we?

First I need to say, determining whether or not you're in the right relationship is

impossible if you're not whole and complete within yourself.

So, the first sign to look for actually has nothing to do with him and everything to do

with YOU.

Ask yourself this: AM I LIVING AND ACTING CONSISTENT WITH MY VALUES?

AM I ALIGNED?

Or are you letting him take the lead of MY LIFE

If your actions and mindset are not aligned with what's important to YOU, than you haven't

given this relationship a real chance, and you need to make it YOUR job to be aligned

and happy within yourself by aligning your values with your mindset and actions.

Until you do that, NO relationship will feel quite right.

Does that mean you need to leave the relationship?

Not necessarily.

But getting yourself aligned should be your first focus, with or without him.

How effective are you with communicating your needs and boundaries?

Are you being your whole self in this relationship or are you starting to lose your sense of

self?

Tell me about it in the comments below.

The Second Sign that you're in the wrong relationship is that he doesn't respect

your values.

Now again, you have to give the guy a chance by communicating your values, what's important

to you and you have to be the police of your alignment.

HOWEVER, if he's trying to talk you out of going to yoga, laughing at you for trying

to better yourself with personal development courses and/or trying to convince you to live

a lifestyle outside of your values, then consider this is the WRONG relationship.

Third sign that you're in the wrong relationship is that you both want different things from

the relationship.

This can be so hard to face, especially if you're having fun now or you're trapped

in the mindset that something is better than nothing.

So I suppose it depends on what stage of life you're in.

The women I work with want to be with the person they are going to share their life

with.

So if that's you, you need to make sure he's on the same page.

If you want kids and he doesn't then you're in the wrong relationship.

If you want monogamy and he doesn't, wrong relationship.

If you want to wait a period of time before getting physically intimate and he's making

you feel guilty for it, then you are in the wrong relationship.

He's not a bad person for any of this, it's just simply not a match.

So let's say it's starting to look like you're in the wrong relationship, what do

you do?

Well first, you need to give this guy a chance to win with you.

If he doesn't know the rules, he can't win, so grab your courage and TALK to him

(not text, not a letter, TALK).

Tell him what your values are and help him understand how he can respect your values

and your boundaries.

Be clear about what you want in the future and find out if he wants the same.

After that, it's fair game.

Now maybe a part of you suspects that this relationship resembles an all-too-familiar

pattern.

For this, I have a free worksheet for you to complete so you can get clear on how your

past is influencing ALL your relationships.

For your own BLAST YOUR PAST workbook, go to the description box and you can access

it from there.

Tell me if this was helpful and if you have other questions!

Write in the comments below.

If you liked this video, click like, SUBSCRIBE and hit the bell and you're welcome to share this with anyone you think would make a difference with.

Extraordinary women Deserve Extraordinary Love.

Take Care

For more infomation >> 3 Signs of an Unhealthy Relationship (AND WHAT TO DO ABOUT IT) - Duration: 4:53.

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Prevent Tire Blowouts :: Buy Quality Tires for Your Vehicle - Duration: 11:04.

Hi there Smart Drivers. Rick with Smart Drive Test today talking with Gary

Krieger a Tireland here in Vernon. Gary's going to give us some information

about saving money and how to buy tires and which tires you should buy and fit

on your vehicle. Stick around. We'll be right back with that information. [INTRO] Hi there smart drivers, welcome back.

Today we're talking with Gary Krieger here at Tierland in Vernon and he's

going to give us some great information about buying tires. Especially now that

we're coming into spring and most of us are thinking about switching off our

winners on to all season tires or summer tires so Gary what are some of the

recommendations that you might have for switching tires now that we're moving

into the spring area here in the northern hemisphere well one thing to

consider is I would suggest at least two sets of tires okay

for one for summer one for winter just does a better job there are some places

where all weather is a new tire that's coming out or you can run it year-round

it's legal for all the mountain passes but I'm a firm believer in the winter

tires for a winter it just does a much better job if you're living in a place

like Vancouver all-weather tires would be fantastic choice right put on okay

yeah so these tires are you talking about that are all-weather tires that

are okay for winter as well they have a symbol on them that will indicate what's

that symbol on those tires that will have a mountain snowflake symbol okay

and that tells so drivers could just look at the yes we'll have M&S on the

tire and it'll also have a four peak or three peak melting snow flake symbol

usually right beside it okay that makes it legal for the winter pass okay

excellent so because here in British Columbia it's not a requirement that we

have to have snow tires but if you're driving on some of the mountain passes

and whatnot then you do have to have them I would highly suggest okay I would

definitely suggest especially if you're in a mountain pass if you're in the

valley bottom no problem but through the mountains you want to have a good tire

okay now in one of the other questions one of my smart drivers sunny asked me

about steel studded tires and we're they're legal to run here in British

Columbia right and we're coming up to the time here that they have to be taken

off the vehicle right we have a we have a date actually for that October 1st

till the end of okay so but that being said if the

weather is still bad in April there are people still running them especially

over the mountain passes okay and what are some of the benefits you and I sort

of had this conversation yesterday what are some of the benefits to steel

studded tires if you are in a place that has a lot of ice a lot of compact snow

and ice I am a firm believer in studs yeah studs dig into the ice yeah rubber

just rides on ice so if you're going up and down them like a Silver Star you'd

like to ski a lot the problem is not going up the star it's coming down the

store so a number one it definitely helps with directional stability but

also stopping ability okay studs will delve and definitely give you a grip but

it comes down to the directional stability and stopping is where they

really benefit you right and that's really what we want to be doing in the

wintertime is actually being able to stop right oh yes I mean it's one thing

to get going but it's another thing to actually get your vehicle stopped yes

with can with control in those types of things yes all right so so that's a good

idea and now here in British Columbia we get a lot of hardpack in those types of

things but if people just wanted to run regular winter tires

I'm not studded tires do what I meant then they're what is there a certain

particular tire that you would recommend for that or well tires that have a lot

of cycling in them so the little cuts that are in the blocks that helps the

tire work like a sponge so it really works well on black ice compacts no it

is okay it makes a big difference so the more site being the more cuts that have

in the tire and also evacuation channels in the tire make a big difference to to

help flush everything out of the tire okay yeah so they get a lot of snow in

the tires in those stations if you can get build-up in the block the the sites

help to flex the block to help it number one give you a grip but also to help

evacuate the tire right right so that the trades are able to do the jobs that

they need to be doing excellent okay so so now we're coming into winter time and

you guys are coming tire land is coming into they're really busy time of the

year with changing back over to all-weather tires for most people yeah

what's the recommendation for people who are trying to book time with tire shops

and they'll fix things to get it's usually best to call at least a day or

two in advance make an appointment that way

it's the least pain okay well you know we like there's some certain days where

we're not that busy other days where we need like 10 guys though that's to make

an appointment you're in a note it's it's almost painless that way okay

perfect perfect now say that somebody needed to come in and they were thinking

that they needed new tires what are some of the signs so for new drivers we a lot

of the smart drivers are new drivers what would be some of the things that

they'd be looking for on tires that would indicate that they needed a new

set of tires on their vehicle well tread depth is is one for sure the

winter tire law and the summer tire laws are different okay in the winter you

have to have five thirty seconds at tread depth in the winter it's two

thirty seconds or sorry in the summer it's two thirty seconds the winter is

five thirty seconds that's right yeah so I like tires that have evacuation

channels so like some of these tires right over here okay they have the

evacuation channels to help get basically the water out of the tire I'm

a firm believer in tires like that okay help is especially for safety that's

what the tires are for you want a good safe tire keep you on the road right

another thing to consider is if you're going to keep the vehicle for four to

five years to save a little bit of money consider it an extra set of rims okay so

it usually takes about two and a half years to pay for that extra set of rims

but it will help you save money down the road okay

well why is that that you're saving money with extra rim well for change in

balance you can be up to about a hundred and ten dollars just to really in extra

set of rims on and off the vehicle or like twenty five thirty dollars so okay

that's where you get your savings okay so that's where you get your safe is

that's an excellent point as well so now we were talking about this previously

about when people are buying all-weather tires what are some of the things that

you know I asked you whether it was money that people were considering in

terms of purchasing new tires or whether it was the quality of the tire and you

said that it was both a little both some people they they want a good economical

tire on their vehicle they like to spend their money inside

else other customers they want the best that money can buy right right and you

definitely get the difference as far as your top line tires they're the quietest

the smoothest the best handling the longest lasting definite benefits when

you're buying the most expensive tires out there there is a difference right

and most of these high quality tires as well they have a high warranty as well

that comes with that tire so yes now one of the things that somebody said to me

some years ago with it there's conditions to these warranties that the

that the vehicle owner has to follow what are some of those conditions that

they have to do to meet to keep their warranty in place with their tires well

the biggest thing is just yeah definitely follow what the manufacturer

is suggesting like rotating the tires check in the linemen to every couple of

years one thing to consider also tires have a shelf life there are good for

usually about seven years most our warranties are good for about five years

okay there's a very odd one where they have a lifetime warranty but that

they're rare very rare and I would think that the lifetime warranty would only

come with sort of really high-end tires that's right okay yes right but one

thing we can say nowadays the biggest thing to consider is tires that are

anything more than eight years old you don't want them on your vehicle okay

we've been having some tire failure issues okay and I do have an example

here if you'd like to see it okay so I just thought I'd bring this as an

example now here's a tire here that has at least 40% tread looks okay yeah the

product code or the Soviet production date are the last four numbers you have

your d-o-t and then it's the last number so this tire was made in the 39th week

of 2007 the tire looks okay tire has decent tread the problem with this tire

here is in the sidewall it's critical in this tire here it just about blew right

off the wheel so this is the problem that we were starting to get with tires

it is critical that you look at the date code on these tires

it is for safety because usually you tire late this you'll be driving down

the road 110 kilometers an hour and they let go there's no warning it just lets

go it explodes so the tire basically you're just driving on the you're just

trying to control the vehicle on the rim just hope that you're on the road not in

the ditch yes okay that's a critical thing nowadays is date

codes on the tires you want to make sure that there are no more than eight years

old get them off the vehicle it isn't worth your life

okay know for sure that is that is tremendously helpful information yeah

okay so that's great so JA I just have one more question for you Gary one of

the things I had a friend who had a brand new vehicle and she got like

20,000 kilometers on the tires and she took the tire into a tire shop nice and

the tires were done good this was kind of shocking information for me that you

have a new vehicle the tires only last 20,000 kilometers some of the brand new

vehicles that are out there they just put cheaper tires on there so yeah

you'll be twenty thirty thousand kilometers for the original set on the

summers or all seasons that's all you'll get so the the tires that we do sell

yeah we can basically fit any budget that you want okay so cheaper tires are

usually good for about fifty sixty thousand kilometers mid about ninety and

then top the line tires are a hundred thousand kilometers and over okay now

say for a mid-sized vehicle for new tires you know say top of the top-line

what kind of price range would I be looking at sort of for that depending on

size a lot of the newer vehicles out there say if you had like a Chevy

half-ton pickup they usually have a 17-inch tire on

their cheaper tires are about $160 top-line tires can go over 300 it all

depends what your weight how much you want to spend yeah

whatever you want yeah it's kind of like fitting accessories to your vehicle

this guy's dilemma you can pretty much put any kind of tire on you walk you

know deeper tread and wider tires and all that sorts of things things that you

can customize your vehicle they're gonna run you a bit more money yeah okay

perfect I think that's some really great information for smart drivers who are

buying new tires and getting used vehicles and those types of things yeah

like there's a lot of information out there I'm asked a lot of questions when

you're going tell them what you do where you go how much you drive or your

commuter are you just in town are you up going up and down the mountains there's

a tire for every purpose holder right yes well that's really great information

we'd like to thank Gary Krieger for talking to us today from tire land here

in Vernon really great information about the tires and the critical role that

they play on your vehicle so we'd like to thank Gary for that thank you very

much

For more infomation >> Prevent Tire Blowouts :: Buy Quality Tires for Your Vehicle - Duration: 11:04.

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WILL BLACK OPS 4 HAVE SUPPLY DROPS? - NEW SYSTEM?! - Duration: 5:24.

Yo what is going on guys its your boy Yogge here and today

For more infomation >> WILL BLACK OPS 4 HAVE SUPPLY DROPS? - NEW SYSTEM?! - Duration: 5:24.

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Why Omega Labyrinth Z Has Been Cancelled - Duration: 4:26.

The Western release of Omega Labyrinth Z is something that Western fans have been looking

forward too, ever since its announcement last November.

However, in an extremely rare move, the game has now had to be cancelled right before its

release due to running into issues with Sony America and Sony Europe.

The title was scheduled for release Spring 2018, but, as explained on PQube's official

website, Sony will no longer allow the game to be released for their systems.

PQube are not able to divulge any further details regarding what it is exactly Sony

took issue with, but its import to stress that this is only an issue with Western Sony,

as the title has previously been released in Japan with no issues.

It is possible that Sony's decision was influenced by the wave of bannings that the game has

seen around the world.

As previously reported, the title has been refused classification in Australia, Germany

and, most surprisingly, the UK - a region that hasn't banned a video game in over 10

years.

These countries cited issues with the RPG's heavy use of various fan service mechanics.

However, despite the release being blocked in at least 5 regions across the globe, PQube

remained committed to getting the game out for all other regions, such as the United

States.

The game was also approved for both an ESRB and PEGI rating, where it was assigned a Mature

and 18 rating respectively.

Despite their commitment, and the clear large amount of money and other resources spent

on getting the game localized and released, Sony then stepped in only at the last minute

and wouldn't approve it.

It was originally planned to be released for both PS4 and Vita, which means this has effectively

killed all previous plans.

Fans noticed something was up last month when the title was removed from PQube's official

website and many people started to receive emails from various retailers, stating that

their order had been cancelled.

PQube was asked to comment on these matters, but unfortunately could only say that they

are unable to comment at this time.

As previously mentioned, for a game to be banned by the platform owners themself is

extremely rare, but it is always something you should keep in mind as being possible,

despite its rarity.

Earlier in the year, Sony did the same thing to a title called Super Seducer for instance,

a game which involved choosing the right combination of dialogue options to pick up women.

That was also cancelled only days before release by Sony, with the platform holder simply commenting

"the game will not be made available".

Nintendo has also occasional done this sort of thing in the past.

The Binding Of Isaac was originally planned for a release on the Nintendo 3DS but, as

the creator explained: "After a long internal debate Nintendo has

decided not to allow The Binding Of Isaac on the 3DS.

As many assumed, the reasons were due to the game's "questionable religious content.""

Luckily for The Binding Of Isaac, though, this would finally change nearly 5 years later,

with its Nintendo Switch release, although, not many further details are known on why

Nintendo later decided to change their mind.

Back to Omega Labyrinth Z, whilst its very unlikely for the situation to change with

Western Sony - this doesn't necessarily mean that PQube are completely out of options.

Funds permitted, it is possible that they could port the game to PC for instance.

There is also the hypothetical possibility of an English release in the South East Asian

market, which is recently becoming a bit of loop hole to allow games to be distributed

in Western counties, in English, whilst avoiding any perceived issues with an official Western

launch.

This was most prominently seen with Dead or Alive Xtreme 3's 2016 Asian English release

for example, but numerous games have followed this trend since and it's very much becoming

a growing practise.

On Twitter, PQube has made clear that haven't completely ruled out looking into other options

and here, for instance, they said "never say never" to a fan asking about a Steam port.

In another Tweet they explained that a PC port would easily be an extra 100,000 on top

of all of the other current costs, though, meaning this wouldn't be as cheap as some

may think.

It currently appears that there no concrete plans have been made but, as PQube has said

"never say never".

One fact that this situation highlights well is the stark contrast between Sony Japan and

Asia vs Sony America and Europe.

It also signifies that there could also be other titles that Western Sony would pull

the plug on, even if a publisher was willing to localize them and even if it was to obtain

ratings from the two biggest Western rating systems, the ESRB and PEGI.

What are your thoughts on this situation?

How do you feel about the release being cancelled and what is you view on this difference between

Eastern Sony and Western Sony?

Please let us know your thoughts in the comments below and, until next time, thank you for

watching.

For more infomation >> Why Omega Labyrinth Z Has Been Cancelled - Duration: 4:26.

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Crash Course Engineering #7: The Law of Conservation - Duration: 10:06.

Thank you to CuriosityStream for supporting PBS Digital Studios.

Imagine that here, in front of me, is a box.

But this is no ordinary box.

It's indestructible, could be any size, and anything could be happening inside it.

Maybe it's making steel from iron.

Or maybe it's burning coal to generate electricity, or creating compounds to be used in medicines.

No matter what's going on inside this magical box, it's our job as engineers to make it the best most efficient box it can be.

And to do that, we'll need to rely on an incredibly basic rule. A law, if you will.

It's called the Law of Conservation, and it says that matter and energy can neither be created nor destroyed.

And we can use this law to figure out both, where our box isn't operating as efficiently as it can be, and how to fix it.

[Theme Music]

Whatever it's doing, our box is what engineers call a system, and what's happening inside it is a process.

Everything beyond the box is known as the surroundings.

Let's say you have an entire steel mill inside this particular box, so the process is converting iron to steel.

Now, iron is expensive.

Running steel mills is expensive.

So if there's something inefficient about the way your box works, you're going to want to know about it – and fix it.

Ideally, whatever you feed into the system at the beginning, is what you get at the end.

Input equals output.

If your box is perfectly efficient,

the law of conservation tells you that the amount of steel you get at the end, should weigh exactly as much as the ingredients you put in.

So if you have 100 kilograms of iron and other ingredients going into your box every hour, you'd also have 100 kilograms of steel coming out.

You know you're not going to get 105 kilograms of steel, because you can't create 5 kilograms of matter from nowhere.

And you can't have 95 kilograms at the end, either, because everything you put into this perfect version of the box is being turned into steel,

and 5 kilograms of matter just can't disappear.

If you're running this system continuously, with ingredients always flowing in and an equal amount of steel always coming out,

you have what's called steady-state.

When a system is steady-state, that means the variables at the input and output remain constant, despite what's happening inside the system.

It's like water flowing through a full tank: if the system is steady-state, water comes out at the same rate it flows in, and the tank stays full.

Of course, we're just talking about what would happen in an ideal situation – if the box is perfectly efficient at steel-making.

The thing is, the real world doesn't usually work that way.

Engineers deal with systems that are way more complex, and they're not going to be perfectly efficient.

But you can use the law of conservation to get a system as close to perfect as possible

– in other words, to get as much output from your input, as you can.

Before we go back to our steel mill, though, let's bake a cake.

The pan will be our system, the oven will be our surroundings, and the cake batter will be our raw materials, or input.

The cake itself will be our delicious output.

Like most processes, we're using this one to make something we want – the cake.

But, again like other processes, it's probably gonna produce some byproducts.

When you burn coal to get electricity, for example, you also get ash, sulfur oxides, and nitrogen oxides.

Steelmaking creates dust from zinc and other metals, which is considered abrasive, hazardous waste.

And don't even get me started on chemical waste from manufacturing pharmaceuticals.

Our cake will probably have some byproducts, too, like if we burn some of the batter on the pan, creating some charred bits that we wouldn't want to eat.

Look, not everyone's a master chef.

There are lots of other ways to end up with leftovers, too.

Sometimes you can't get all of your raw materials to react or turn into what you want – like if there's some batter in the pan that doesn't get cooked.

Some of the final product can also get stuck in the system.

Maybe some of the batter spilled onto the oven racks.

Any of these examples could be waste since you couldn't simply separate them back into their initial parts to use them as input next time.

There's also the possibility our raw materials were contaminated, which could easily end up in our final product.

When we cracked open the eggs, for example, some small pieces of shell might have fallen into the batter,

which means we'll probably still find them when we try a slice of finished cake.

You know, on second thought, maybe I'll pass.

So, clearly our cake-baking process has a lot of room for improvement.

Engineers define problems like these in terms of conversion and yield.

Conversion describes how much of our initial input was used in the process.

If our system has a conversion rate of less than 100%, it means you'll have some leftover or waste.

Now that our cake is done, let's go back to the steel mill in a box.

If you had 100 kilograms of iron and other ingredients going in, and a 60% conversion rate,

that means you'd have 40 kilograms of iron left over at the end of the process.

That's a lot of wasted iron!

Yield, meanwhile, describes how much of the final product you were able to get from your initial input.

So if your box has a 30% yield, 100 kilograms of raw materials would get you 30 kilograms of steel, and 70 kilograms of waste.

The most basic way to think about a system is in terms of "balance".

Engineers measure the values that go in and the values that come out, and if there's a difference, they'll try to figure out what's causing it.

But conversion and yield only cover the beginning and end of the process.

Engineering, like life, is usually not that simple.

If you have a system that's not in steady-state, then you probably don't have the same amount of mass coming in and out.

Real-life processes are messy, and stuff gets stuck along the way.

That's accumulation, and as engineers, we can use it to keep track of the differences between what's coming in and what's going out.

The basic idea is pretty simple: if you subtract your output from your input, you get your accumulation.

If you're measuring all this in terms of mass, that simple equation is probably all you need.

Mass goes in, and whatever mass doesn't come out at the end, is stuck inside the system.

But when there are chemical reactions happening inside the system – which there often are –

it can be more useful to think about accumulation in terms of molecules.

During a process, your raw materials might go through a chemical reaction that generates some molecules that don't end up in your product.

Or a reaction might consume some molecules that are hanging around inside the system and weren't part of the input.

To keep track of where all your molecules are, and which of them are accumulating inside the system, you need two more terms: generation and consumption.

To calculate accumulation, you'd take your input and subtract the output like usual.

But then you'd also add the molecules being generated within the system by chemical reactions, and subtract any molecules being consumed.

Whatever's left over is what's accumulated inside the system.

This equation is essential to engineering.

Even in its simplest form, engineers can use this equation to figure out how to improve a system.

So let's see how we can improve ours!

The steel mill in our box has some raw materials flowing in and steel flowing out.

As engineers, our goal is to make as much steel as possible at the end of the process.

Let's say we begin with 100 kilograms of raw materials with a 70% conversion rate,

which means we're only making 70% of what's possible, or 70 kilograms of steel.

Not bad, but not great.

We'd be losing out on 30 kilograms of raw materials, and probably a good bit of money!

This is where we'll need to problem-solve as an engineer and figure out how to make the process better.

How about a recycling system?

We can introduce a separator at the end of our system to sort out any leftovers.

Then we can run that stream of unused raw materials back into the beginning of our process.

We already have 70 kilograms of steel and 30 kilograms of iron and other ingredients that weren't used.

Let's send those 30 kilograms back.

Now, instead of 100 kilograms being fed into the system, we have 100 kilograms plus the leftovers from the previous cycle.

So, even though we still have a 70% conversion rate, we're still getting more steel from the same amount of raw material, than we were before.

But what if our raw materials aren't perfectly clean?

What if we have contaminants?

Sometimes contaminants can lead to big problems, literally ruining machines and halting production.

It can be very serious and costly.

For example, soda bottling plants have had to shut down production because of possible chlorine contamination.

With our steelmaking example, let's assume the contaminants are relatively harmless and won't react with anything.

We'll keep using our recycling system from before, but now we'll also need a 'purge system' to filter out the contaminants.

If we don't get rid of them, we'll be passing them back while adding new contaminants during the next cycle.

As the contaminants build up, we'd run into more and more problems with our machines and tools.

Remember, just because we're following the Law of Conservation, or any other principles of engineering for that matter,

it doesn't mean everything is working out the way we want it to.

As engineers, we'll encounter limitations like these and many others.

But with clever designs, we can work around them.

Engineering is all about testing our limits and pushing them as far as we can until we reach something truly extraordinary.

So today we learned all about the law of conservation, beginning with simple, steady-state systems.

We then introduced the terms conversion and yield, showing how they apply to a system.

We ended with accumulation and covered how generation and consumption can affect how much accumulation there is in a system.

I'll see you next time, when we'll learn all about reversibility and irreversibility and how they affect engineering.

Thank you to CuriosityStream for supporting PBS Digital Studios.

CuriosityStream is a subscription streaming service that offers documentaries and non-fiction titles from a variety of filmmakers, including CuriosityStream originals.

For instance, CuriosityStream has "Stephen Hawking's Favorite Places"

a series where renowned physicist Stephen Hawking takes a flight of epic proportions to visit his favorite places in the Universe.

You can learn more at curiositystream.com/crashcourse and use the code crashcourse during the sign-up process.

Crash Course Engineering is produced in association with PBS Digital Studios.

You can head over to their channel to check out a playlist of their latest amazing shows,

like The Origin of Everything, Deep Look, and Eons.

Crash Course is a Complexly production and this episode was filmed in the Doctor Cheryl C. Kinney Studio with the help of these wonderful people.

And our amazing graphics team is Thought Cafe.

For more infomation >> Crash Course Engineering #7: The Law of Conservation - Duration: 10:06.

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Nhạc Không Lời Rumba Ngọt Ngào Êm Ái II Nhạc Vàng Chọn Lọc II Organ Không Lời - Duration: 56:57.

For more infomation >> Nhạc Không Lời Rumba Ngọt Ngào Êm Ái II Nhạc Vàng Chọn Lọc II Organ Không Lời - Duration: 56:57.

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Lab Notes: Sodium progress report and dimethyl dioxane troubles - June 2018 - Duration: 9:39.

Greetings fellow nerds.

So this june has so far had very little actual progress despite a lot of work being done.

So first a brief recap.

I've been trying to make sodium metal by the alcohol catalyzed magnesium reduction approach and thus far i've been rather successful.

Turns out that all you need to do is mix together magnesium metal, sodium hydroxide, a percent of tertiary alcohol and use baby oil as the solvent.

Then you heat the mixture on a hotplate up past 200 celsius, preferably 340 celsius and stir.

After three days you get sodium metal.

Of course there is a lot of processing with dioxane to separate it from the slag but for the most part this process does work.

Unfortunately, there are some major issues.

One is time, spending three days per reaction to generate about ten grams or so of sodium is, to put it lightly, not a very efficient use of time.

That's one of the big reasons this month has been devoid of videos.

I've been wasting a lot of time on sodium related experiments.

I really need to build a second fume hood so i can do more experiments at once.

The second issue is damage and cost.

The reaction mixture is very damaging to glassware.

Expensive borosilicate laboratory glassware.

Sodium hydroxide is well known for dissolving silicon dioxide, including the silicon dioxide that glass is made out of.

In fact we exploit this property to make sodium silicate as shown in previous videos.

So i've been trying to figure out how to mitigate this problem.

The obvious and most straightforward solution is simply not to use glass at all.

Most ferrous metals, like steel, are completely immune to molten sodium hydroxide.

As well as a lot of non-ferrous metals like titanium and copper.

In fact among all the common metals, aluminum is probably the only one that's incompatible.

The other incompatible metals like magnesium aren't encountered that often as container materials.

But for now i'll keep using glass.

Glass lets you see what's going on and easily let's you stir the mixture by magnetic stirring.

So i'm going to need to figure out a way to protect the glass.

My first idea was to coat the glass with something.

Maybe a sacrificial coating of more glass.

After seeing the sodium silicate harden into a glass like solid in one of my previous videos,

I thought it might be applicable to my current problems with making sodium.

I poured in a small amount of sodium silicate, rolled it around until i got a nice coating, and heated it dry.

The small amount wasn't enough to crack the glass and it did indeed harden to a very hard and durable layer.

Unfortunately the boiling produces lots of obvious holes.

I think though this is still a promising route, perhaps the right mixture of chemicals can produce a thin solid cement.

But for now i'm going to put this route on the backburner and explore alternatives.

Now i know at relatively low temperatures the destruction of glass is fairly slow.

While highly susceptible substances like silica based cat litter can dissolve just at room temperature.

Quality borosilicate laboratory glassware is fairly resistant.

Unfortunately, running the sodium production reaction in mineral oil at modest temperatures around a hundred celsius doesn't seem to work.

Maybe the sodium alkoxide isn't reactive enough or maybe the magnesium isn't reactive either.

Whatever it is low temperatures doesn't seem to work.

At least the glass isn't destroyed.

But let's go with the hypothesis that the sodium alkoxide isn't soluble in mineral oil at these temperatures.

How do we solve that? Well, if we can't raise the temperature, maybe we can use a more polar solvent, something that can dissolve sodium alkoxide.

But we have to remember that sodium will be present and most polar solvents react with sodium, we need a polar solvent that doesn't react with sodium.

My first instinct was to attempt dioxane.

Dioxane is much more polar than mineral oil and also seems to have special properties for separating sodium from magnesium oxide slag.

Now this experiment already failed last year but at that time i didn't have the same insight as i do now

So i attempted the reaction again with stirring as well as a sodium metal jumpstart.

As usual i had sodium hydroxide and a stoichiometric excess of magnesium metal as well as a milliliter of tertiary alcohol.

In my case i used 3-ethyl-3-pentanol since i had such good results with it.

I let i run for a few days but nothing happened.

I also had a bubbler connected but noticed no hydrogen.

My reaction failed as before.

Oh well, it was worth a shot.

Now dioxane boils at about 100 celsius so maybe the temperature is just too low as per our theory.

We can't heat it higher or the dioxane would boil off.

So my next thought was to try and get a polar solvent that was higher boiling than dioxane.

Now we made dioxane using ethylene glycol, how about we use propylene glycol and make dimethyl dioxane?

I couldn't find reliable literature data on the boiling point but i thought it would be higher and worth an attempt.

Unfortunately i thought wrong.

I got myself some propylene glycol based antifreeze and proceeded to condense it to make dimethyl dioxane in a very similar fashion to making regular dioxane.

I mixed it with some sulfuric acid, boiled off the water and distilled over the dimethyl dioxane.

However my yield was terrible, most of it converted to tar.

My original propylene glycol must have had impurities in it that encouraged tar formation.

So I proceeded to distill and purify all of my propylene glycol first.

It has a high boiling point of 183 celsius and doesn't form azeotropes with water, so purification was rather straightforward if slow.

At the end of the distillation i had a lot of residue leftover, this would explain the excessive tar formation.

So now with my purified propylene glycol i proceeded again to perform an acid catalyzed condensation reaction and produced dimethyl dioxane.

This time it worked a lot better and produced a much higher yield than before.

Okay, so far so good.

Following the old procedure to make regular dioxane i added some acid to hydrolyze side products and proceeded to distill it again.

Unfortunately this backfired spectacularly.

It turns out that dimethyl dioxane is highly susceptible to acid catalyze hydrolysis,

much more so than regular dioxane on which this procedure is based.

I ended up destroying most of my dimethyl dioxane and remaking propylene glycol as well as tar.

Learning from that blunder i repeated my synthesis and spent another couple of days making dimethyl dioxane again.

This time, to purify it i mixed it with potassium hydroxide and attempted base catalyzed hydrolysis of impurities.

Turns dimethyl dioxane is much more resistant to bases.

Now I know there are some impurities that are also resistant to bases

but i figured that if they could resist reacting with potassium hydroxide

then they would also likely resist reacting with the sodium hydroxide and magnesium metal reaction mixture.

So i proceeded to distill my reaction mixture.

Unfortunately the lab gods decided to make an example of me again and ruined the fractional distillation

by causing it to foam so much that it actually reached up the 150cm fractional distillation column and spill over.

Needless to say i was very disappointed.

Fractional distillations take hours to do and when there is a major upset like this you have to start all over again.

Eventually after a few more false starts, i distilled again with much smaller quantities and using larger apparatus to contain the foaming.

I was able to obtain dimethyl dioxane.

Unfortunately my bad luck didn't stop there.

It turns out the boiling point for dimethyl dioxane is around 117 celsius.

That's not much better than regular dioxane.

It probably wouldn't give any significant improvement.

But to be absolutely certain it wouldn't work i ran the reaction anyway and again, nothing happened.

This was a dead end.

All of that work and failure for nothing.

Do you guys still want me edit a video on how to make dimethyl dioxane even though it's useless? I have all the footage.

Let me know in the comments.

Anyway, that was my progress for making sodium this month.

Needing a diversion so i didn't go on a homicidal rampage from the frustration,

i decided to put that project on the back burner and revisit my pyrimethamine synthesis.

To round out the original video i wanted to product it using lab chemicals.

Rather than using the original domestic chemical route that's more complicated than NFL play night analysis.

If we could use lab chemicals then this much simpler two step route should be accessible.

So i've already begun work on the first step, performing the grignard reaction between ethyl magnesium bromide and p-chlorophenyl acetonitrile.

It seems to be working, but i won't know for certain until i run the nuclear magnetic resonance spectroscopy analysis.

I'm still processing this reaction.

So that's what i've been up to for the month of June.

sorry there are no actual videos.

I think i'm going to rename these progress report videos to Lab Note videos.

I think that better describes what they are as i'd also like to incorporate separate experiments, abandoned experiments and tangents.

Basically a video version of what you find in a lab notebook.

Ah well, let me know what you think.

And apologies again for june being a relatively dead month.

For more infomation >> Lab Notes: Sodium progress report and dimethyl dioxane troubles - June 2018 - Duration: 9:39.

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DIVINE 5 SPEC VS JUG LION AM SHAM - Duration: 5:46:36.

For more infomation >> DIVINE 5 SPEC VS JUG LION AM SHAM - Duration: 5:46:36.

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Mother, 9-year-old son reunited after judge's ruling - Duration: 1:17.

For more infomation >> Mother, 9-year-old son reunited after judge's ruling - Duration: 1:17.

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Omaha teenager promoting 'firework fight' on Facebook - Duration: 2:24.

For more infomation >> Omaha teenager promoting 'firework fight' on Facebook - Duration: 2:24.

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'Five dead' in mass shooting at Maryland newspaper building - Duration: 12:37.

Five people have been killed and more than a dozen injured during a mass shooting at Maryland's Capital Gazette newsroom

Police were on the scene within 60 seconds of the call of an active shooter at the newsroom in the 800 block of Bestgate Road, Annapolis, at around 2

40pm.Acting police chief William Kamph confirmed five people had been killed and many more had 'serious injuries' in the attack

The suspect, who has not been named, has been taken into custody. Police say he was the sole shooter and that the building - which was evacuated during the attack - has now been secured

 No motive has yet been given for the shooting. Phil Davis, a court and crime reporter for the Gazette, said that a lone gunman had shot through the glass door of the offices and then opened fire on the newspaper employees

'A single shooter shot multiple people at my office, some of whom are dead,' he tweeted, while he said he was waiting to be interviewed by police

  Scroll down for video  'Gunman shot through the glass door to the office and opened fire on multiple employees

Can't say much more and don't want to declare anyone dead, but it's bad.'There is nothing more terrifying than hearing multiple people get shot while you're under your desk and then hear the gunman reload

'Describing the moment as like being in 'a war zone', Davis said he and his colleagues were hiding under their desks, listening to the gunman firing and reloading until there was sudden silence

'I don't know why he stopped,' he said.Moments later the police arrived, and surrounded the shooter

Officers were able to take the suspect down and into custody although Kamph could not confirm whether gunfire was exchanged during the arrest or if the suspect was injured

'The suspect is still being interviewed by police,' he said. 'The investigation has just started

'   Police were also unable to confirm whether reports that the shooter had used a shotgun were accurate

They did confirm, however, that the building was secure but would remain closed as crime scene investigators got to work

 Davis added in an interview, with the surrounding press outside the newspaper's headquarters, that while he wrote about mass shootings as part of his crime beat, it was another thing to experience one first hand

'I'm a police reporter. I write about this stuff - not necessarily to this extent, but shootings and death - all the time,' he said

'But as much as I'm going to try to articulate how traumatizing it is to be hiding under your desk, you don't know until you're there and you feel helpless

' The shooting sparked a huge police response, with local departments joined by the FBI and Bureau of Alcohol, Tobacco, Firearms and Explosives

  An intern with the Capital Gazette, Anthony Messenger, tweeted at 2.43pm there was an 'active shooter 888 Bestgate please help us

' Aerial footage shows people being led out of the building with their hands raised

 Medevac helicopters were also at the scene.John McNamara, who has worked for the Gazette and is the editor of the Bowie Blade-News and the Crofton-West County Gazette, has been confirmed among the shooting victims

It is not clear whether he was injured or a fatality. Gazette reporter Danielle Ohl added that her colleague Rachael Pacella was among the injured in hospital

  At least one injured victim is being treated at the University of Maryland Medical Center

   Anne Arundel Police confirmed that the building had been evacuated and staff have been told to reunite with their families at a nearby Lord & Taylor store

Maryland Gov. Larry Hogan said during a press conference he was 'absolutely devastated to learn of this tragedy in Annapolis

'I am in contact with County Executive Steve Schuh, and @MDSP is on the scene assisting @AACOPD

Please, heed all warnings and stay away from the area. Praying for those at the scene and for our community

''Your heart goes out to all the people that lost their lives. We have had several fatalities and we have had several people hospitalized

' SHOOTING COMES TWO DAYS AFTER MILO YIANNOPOULOS SAID HE 'CAN'T WAIT FOR VIGILANTE SQUADS TO START GUNNING JOURNALISTS DOWN' As news of the Capital Gazzette shooting broke on Thursday, many on Twitter pointed out that the tragedy comes just two days after conservative provocateur Milo Yiannopoulos cheered the idea of journalists being murdered

When asked to comment on two different stories being written by The Daily Beast and The Observer, the alt-right poster boy responded with the same one sentence:'I can't wait for vigilante squads to start gunning journalists down on signt

'When asked by the Observer to elaborate about what had upset them about their story, about a popular GOP watering hole, Yiannopoulos replied that it was his 'standard response to a request for comment'

(The Daily Beast's story was about the UK Independence Party.)It's still unclear what inspired Thursday's shooting

DailyMail.com reached out to Yiannopolis for comment, and he responded, saying there was no evidence, as his critics said online, that he may have inspired the attack

 In a longer statement on his website, he said if anyone is to blame, it's the two outlets that published his statements, which were meant to be private

 'I sent a troll about "vigilante death squads" as a *private* response to a few hostile journalists who were asking me for comment, basically as a way of saying, "F*** off

" They then published it.'If there turns out to be any dimension to this crime related to my private, misreported remarks, the responsibility for that lies squarely and wholly with Will Sommer of the Beast and the Observer's Davis Richardson for drumming up fake hysteria about a private joke, and with the verified liberals who pretended they thought I was serious,' he said

 The 33-year-old Brit was forced out of his role as a senior editor at Breitbart in February 2017, after interviews surfaced of him expressing sympathy for pedophiles

Since then he has self-published an autobiography titled 'Dangerous' which became an Amazon

com best seller. Simon & Schuster was originally supposed to release the book, but ended the business deal over the pedophile scandal

 White House spokeswoman Lindsay Walters said President Trump has been briefed on the shooting and 'our thoughts and prayers are with all that are affected

' Sen. Chris Van Hollen added in a tweet: 'My heart is with the families, friends, and loved ones of the victims as we learn more about this terrible situation

We must unite to end the violence.' The Gazette is owned by the Baltimore Sun Media Group, which is owned by Tronc, inc

 .The NYPD says it is stationing officers outside the headquarters of major newsrooms throughout the city in the wake of the shooting

 The Capital Gazette is a daily newspaper that serves the city of Annapolis, Maryland

It's sister newspaper, The Maryland Gazette, is one of the oldest American newspapers

 Founded in 1884, it has a circulation of more than 30,000 daily and 35,000 for the Sunday edition

For more infomation >> 'Five dead' in mass shooting at Maryland newspaper building - Duration: 12:37.

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Nebraska media outlets launch First Amendment education campaign - Duration: 1:36.

For more infomation >> Nebraska media outlets launch First Amendment education campaign - Duration: 1:36.

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What it's Like to Speak at VidCon | Less Than Famous Panel 2018 - Duration: 11:33.

So last year, I went to VidCon for the very first time,

and honestly, I had such a good time that I didn't think that anything could really top that initial experience.

But I was so wrong.

This year, I have friends to hang out with, a sweet place to stay in, and I'm not gonna get a sunburn.

Um, just because it says that it has aloe in it...

does not mean that you should rub it all over your sunburned body.

and finally, I was chosen to speak on the Less Than Famous panel this year at VidCon.

Lindsay Daly?

Yes, D-A-L-Y.

Put it on your right hand

...and you're all set, you can write your name on there if you like.

Okay!

You're all set!

Thanks very much!

You're welcome!

So uh, I just got my speaker pass.

It feels really weird, honestly.

Do I look good in it?

So maybe this is disgusting, some people are 100% going to judge me for this,

but in my hurry to pack, I neglected to pack more than the underwear that I was wearing at the time.

So uh...I've just been wearing the same pair every day.

Washing them every day and drying them every day.

You know, at least it's not as bad as putting...

hair gel on your sunburn, so...I'm fine.

I'm doing just fine.

By the way the panel is later today, so, that's a thing.

You know honestly, it's a good thing because I think I'm wearing my lucky underwear for this.

I've found at least one of the other people, this is Bella

Wassup!

and uh, we're gonna go take free food from the lounges now, so...

You know it!

You already know what it is.

So we're in the lounge having breakfast and uh, they have fortune cookies here,

which each have very unusual fortunes inside them.

Okay, it says...

The road to riches is paved with "Like and subscribe"

Oh my GOD.

Like and subscribe to Lindsay Daly.

Oh, no! [Laughs]

[Makes sloth noise]

I love slides.

I'm such a child.

So, the panel is in about three hours,

I just decided to take a little break and hang outside by myself for a second.

Cause, I guess,

you know the thing about VidCon really is like...

I don't know, like, you're

I mean at least this year, like, I'm never alone.

Uh, whereas last year I felt like I was alone almost all the time,

because I didn't know anyone, so...

yeah I just felt like I'd take a little bit of a break.

And try not to freak out about speaking today.

But...I don't know. We'll see how that goes.

They have us, uh, corralled in this room before we go and speak, and the panel is in...nine minutes.

So...yeah. Yeah.

...and I hope you have a good rest of your VidCon, everybody!

Panel is over. I was...sittin' up there and sh*t.

So, that was it. Um, that was the panel.

I'm just back now, but I did make one final stupid mistake other than the whole underwear fiasco,

and that is the fact that I forgot to bring my SD card reader,

but luckily, Amazon Prime is our friend,

and uh, I got same-day delivery, b*tch!

Shouldn't have thrown that, that costs like $100, f*ck.

I'm more sweaty than is probably acceptable right now,

and I should probably go edit this video, so...see ya.

There were really so many different things about this year in particular that made it great,

including spending like 80% of my time in the pool,

and hanging out with these fun people at this amazing house.

and obviously, speaking was a huge privilege,

I mean, I was f*cking honored that they would choose me.

and with this yellow badge of honor,

um, I was able to get into all these exclusive lounges and parties,

and stuff like that, including access to a puppy corral?

So since I have the speaker pass, I'm allowed to go to this thing where they close down the expo hall

for just like industry people and stuff like that, featured creators.

So I'm just checking everything out now, finally for like the first time down here,

um, it's pretty cool!

and I also got to pet puppies, so.

This is the best day of my life.

The pass also allowed me into parties at the Hyatt,

which basically just enabled me to gawk up-close at some people like Elle Mills, and Phillip DeFranco,

and Hannah Hart, the Try Guys, and so many, so many other people.

Actually it's kinda funny, I think my experience this year at VidCon was almost kind of what TanaCon promised,

which is just that you would be walking around among your favorite creators and stuff.

Clearly, that's why this doesn't work, I mean,

for me to get that experience, this was like a once-in-a-lifetime opportunity, so...

it didn't even feel real at the time.

I don't really have like pictures with anyone or anything like that, uh, I had opportunities, but...

it's really not what I care about.

What I really care about is getting to talk to the people behind some of my favorite videos

that I watch every single day online.

With that, I actually got the chance to talk to two people in particular who I was like...very pleased about.

The first one is Caitlin Doughty or Doughty, I'm not 100% sure how you say her last name, but

but on YouTube she's known as "Ask A Mortician".

I saw her in the expo hall when it was closed down for like the featured creators

and people with yellow badges and stuff.

And um, so I just went up to her and said hello, told her how much I love her videos, and that I'd read her book,

yeah it was just like a really nice little moment, and it was super cool to get to meet her in person;

she is super tall, by the way.

The second person that I got to meet I think was honestly my favorite whole part of VidCon this year,

which was my creator chat with Binging with Babish,

and meeting him was just really fun, he's exactly like he is in his videos,

And uh yeah, I got to ask him a lot of great questions,

including asking if he had ever considered making Daniel Day-Lewis' breakfast from "Phantom Thread".

A welsh rarebit.

With a poached egg on top.

Please.

Not too runny.

And bacon.

Scones.

Butter. Cream.

Jam.

I really wanted to enjoy this opportunity to the fullest, so I went to everything that I could,

and I'm pretty tired after this weekend, but

I just wanted to say thank you, to VidCon, I guess,

Like...sh*t, thanks for picking me!

Anyways, I don't know if anything could possibly top this year at VidCon, but um, I guess we'll just have to see.

For more infomation >> What it's Like to Speak at VidCon | Less Than Famous Panel 2018 - Duration: 11:33.

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Heat wave to take hold - Duration: 3:11.

For more infomation >> Heat wave to take hold - Duration: 3:11.

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Immigration rally planned for Boston Common this Saturday - Duration: 1:37.

For more infomation >> Immigration rally planned for Boston Common this Saturday - Duration: 1:37.

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STA bus driver cited following Wednesday crash near high-voltage transformer - Duration: 2:11.

For more infomation >> STA bus driver cited following Wednesday crash near high-voltage transformer - Duration: 2:11.

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Extreme heat takes a toll on firefighters - Duration: 0:44.

For more infomation >> Extreme heat takes a toll on firefighters - Duration: 0:44.

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Il "ciclone" Casalino rivoluziona la comunicazione del governo - Duration: 3:17.

 Un'informazione-comunicazione così non si era mai vista a palazzo Chigi. Nei primi due vertici europei sotto la sua gestione, Rocco Casalino (portavoce del presidente del Consiglio, un passato al "Grande Fratello") ha letteralmente rivoluzionato l'informazione paludata del passato, che a seconda dei presidenti del Consiglio prevedeva o totale assenza di informazioni ai giornalisti (governi Renzi e Gentiloni) o un sistema mirato nel filtrare le notizie più o meno utili al governante di turno, ma anche ai media, un metodo a suo tempo seguito dai governi Berlusconi, Prodi, D'Alema, Monti, con un atteggiamento più aperto da parte del governo Letta

      Nel pre-vertice di domenica scorsa e in quello in corso, entrambi a Bruxelles, Casalino ha proposto invece un metodo nuovissimo e più trasparente: aggiornamenti costanti degli eventi in corso

O attraverso la sua chat, oppure con briefing condotti in prima persona, per veicolare informazioni sui discorsi e sull'attività del presidente del Consiglio

Comunicazione piene anche di osservazioni personali e di qualche gag da gigione: «Poi c'è una cosa che…, ma non ve la dico, dai…»

Per non parlare del "numero" nel vertice in corso: si sono avvicinati a Casalino diversi giornalisti tedeschi e lui si è messo a parlare nella loro lingua

Nato in Germania da genitori emigrati (il papà pugliese era un operaio), Casalino ha fatto le scuole superiori nel Paese di Angela Merkel

      LEGGI ANCHE       Un sistema, quello dell'informazione a getto continuo, immaginato per aggiornare i giornalisti, ma indirettamente anche per provare ad orientare il sistema informativo e gli eventi in corso

Nel mini-vertice a 16 di domenica scorsa è bastato che Casalino (come fanno abitualmente i portavoce di tutti i premier) informasse i giornalisti italiani sul discorso inaugurale di Conte, per suscitare l'irritazione dei francesi e del presidente Macron in persona

Un diluvio di informazioni (a disposizione dei giornalisti, che le possono selezionare) talmente tambureggiante che ogni tanto si crea qualche malinteso

Nella chat, a chi gli chiedeva se fosse vera una certa informazione, Casalino ha risposto con un dito medio, una risposta "adolescenziale" che ha cancellato nel giro di qualche secondo, ma che è finita nel notiziario Ansa

Casalino ci è rimasto male: «Lavoro 18 ore al giorno, ho 73 chat e se cancellare un emoticon diventa una notizia, mi arrendo»

 

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