Thứ Ba, 24 tháng 4, 2018

Waching daily Apr 25 2018

Bruder tractor | Kids video | World of toys channel

For more infomation >> BRUDER TRACTOR broken TRACKS! Action video for kids - Duration: 12:31.

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ÂM BẢN 3D - BẠN ĐÃ THỬ NGHE BÀI HÁT NÀY CHƯA? NGHE THỬ ĐI !!! NGHIỆN ĐẤY - Duration: 3:46.

For more infomation >> ÂM BẢN 3D - BẠN ĐÃ THỬ NGHE BÀI HÁT NÀY CHƯA? NGHE THỬ ĐI !!! NGHIỆN ĐẤY - Duration: 3:46.

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CSW DASH - POLOLO INSTRUMENTS - Review [sub eng fra] - Duration: 4:27.

Hi everyone and welcome to the FLOEB channel !! we meet again today for another review with the dashboard

CSW of pololo instruments !! I show you in detail, let's go!

Here in detail, the csw dash of pololo instruments, the dash measures 13.7

cm wide, 8 cm high and 4 cm deep, it weighs

246 g

I start with the front panel, a 4.3 inch non-touch LCD screen

however, it is possible to ask leopoldo for an optional touch screen. around the screen, a 2 mm thick carbon plate

with markings

engraved and hand-painted. here are the inscriptions of the nearest, it is very clean, everything is engraved

and hand-painted, there is a lot of work, it's really very fine

very meticulous

a great job

we notice the detail with the "." after chg !! everything is detailed, it's really beautiful! wonderful work

three knitter buttons with a good feeling

four small screws, with capsules

in pvc, buttons that we can configure

for example on z1, for the screen change with + and -

we note that the carbon plate is 3 mm recessed, there is a slight border on the screen

the csw is made of high density pvc

machined cnc !! nice design with beautiful curves

on the top of the screen there is a 1.8 cm pvc offset

on the edge of the screen, a border of paint, everything is done by hand

for the edging, it is used fluorescent paint, it is really very clean

very pretty!

And on the back the pvc is chamfered on the periphery! and the dash received five layers of paint

and a layer of matte varnish

2 carbon engine mounts 2 mm thick with a 10 cm center distance

the supports have a height of 5 cm and can be adjusted in height !! a possible setting on

1.5 cm !! then 2 usb cable, a length of 1 m40, 1 cable

usb for screen and 1 cable for knitter buttons

the screen is compatible with the software

z1 and gforce of srh

possible that it is also compatible with other software !! the price for 1 dashboard csw of pololo instruments is €390 !!!

here! this review is over !! the positive points that I give: the quality of finish

engraved markings

and hand-painted !! knitter buttons

a nice design !! and the negative point that I give for this dashboard is the price, I find the price excessive!

here! I will put you the link in the description of the video if you are interested in this dashboard csw from pololo instruments !!

I thank leopoldo for the confidence he gave me to carry out this review

do not hesitate to like my facebook page, to subscribe to my youtube channel and I give you an appointment for a

next review !!! BYE !!!!!

For more infomation >> CSW DASH - POLOLO INSTRUMENTS - Review [sub eng fra] - Duration: 4:27.

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Nhảy Shuffle Dance/ Cutting Shape Cực Chất (Team Shuffle VN) - Duration: 0:46.

For more infomation >> Nhảy Shuffle Dance/ Cutting Shape Cực Chất (Team Shuffle VN) - Duration: 0:46.

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Vlog April 2018 - Failed experiments and work in progress on making alkali metals - Duration: 5:15.

Greetings fellow nerds.

So it's been over three weeks since my last video and i vow to keep you updated as to what i'm up to.

I've been very busy these past weeks but it's a good kind of busy.

First i spent a couple of weeks doing chemistry for a TV show.

I'll be honest, I look like an idiot.

And not the endearing kind, but the stupid and pretentious kind.

As the old saying goes, better to remain silent and be thought a fool than to speak and remove all doubt.

Anyway, if that TV show goes to air i'll let you know so you can cringe at how pretentious i sound.

Moving on i've been doing alot of chemistry and not all successful.

First i needed to replenish my supplies of ethyl propionate and trimethyl orthoformate.

Now i already showed you how i made them but i want to show some alternative methods for didactic value.

In particular i tried to make ethyl propionate by the amide approach.

Basically, convert propionic acid into propanamide, then react propanamide with ethanol to make ethyl propionate.

In theory this should give higher yield because the ammonia product is very volatile compared to water.

It should boil out and thus drive the reaction forward as it's lost.

So i tried making propanamide by reacting urea and propionic acid and that seemed to work somewhat.

I had a lot of condenser clogging problems due to ammonium carbonate solidification but that was to be expected.

Once i had the propanamide i added ethanol directly refluxed and tried to distill off the ethyl propionate product but there was none.

I probably needed an alkaline catalyst.

So i added some sodium hydroxide and tried that but that didn't work either.

I'll be honest i was a very reckless and haphazard with my approach and didn't bother purifying the propanamide before i added ethanol.

I know the process does work since it's in the literature, but it appears you actually need to put the work in and properly purify the reagents as you make them.

I wanted to see if this process was better, easier or faster than the molecular sieve approach i showed last year.

It is not.

If the molecular sieve approach does everything, requires very little effort and actual work, and still gives awesome yield, then there is really no point in wasting time on other methods.

So after spending a week on it i abandoned the project.

We have more interesting things to try.

Next i made trimethyl orthoformate to replenish my supplies.

I didn't film it though since it was pretty much the same as my old trimethyl orthoformate video.

However, i did change the procedure a bit and instead of using molecular sieves to make sodium methoxide i used sodium metal.

It's faster and higher yielding than using molecular sieves.

Since i need to make another batch anyway let me know if you want me to film it this time using the sodium metal approach.

I'll be honest, the individual parts to the procedure are nothing you haven't already seen before.

They're just being put together differently.

So moving on to the main attraction, making alkali metals.

You've already seen me spend a long time making alkyl halides and then performing grignard reactions to make medium and heavy alcohols.

These are catalysts to making alkali metals by the magnesium reduction method.

The advantage of using catalysts is they should work under mild conditions and you don't need to set things on fire.

The amateur community was already very successful in making it work with potassium but not sodium.

So i tried doing it with my favorite solvent for this process, tetrahydronaphthalene.

I had good success with it several years ago when i was making potassium but found it didn't work with sodium.

I redid my procedures and again failed as before.

But this time i thought it was because my tetrahydronaphthalene was impure.

It did have a yellow tinge so to purify i used sodium destruction.

This was not something i had amateur access to during my initial experiments.

Sodium destruction works with all kinds of inert solvents like ether, mineral oil, even triethyl amine so i thought it would work here.

I refluxed with sodium, got tar that i presumed was the impurities and then distilled.

I used this purified tetrahydronaphthalene for further experiments but again i failed.

After several days of failures i was starting to suspecting the solvent so i put fresh sodium in and refluxed..

Then i found the culprit.

More tar kept coming out.

The tetrahydronaphthalene is either grossly impure, or i suspect, the tetrahydronaphthalene itself is reacting with the sodium.

It's not so inert afterall.

Now the reaction seems to be extremely slow and produces only tiny amounts of tar even after several hours of refluxing.

So for the most part tetrahydronaphthalene is considered inert.

But when working with a catalytic reaction even a small amount of impurities or tar can destroy it.

Whatever the case may be, persistent impurities or reactive tar formation,

Any sodium made would be destroyed again.

I'll discuss this further including why potassium seems to work once i finish my alkali metal research.

For now though work is still in progress.

I'll either get sodium metal by the catalytic approach, or have a comprehensive failure analysis video for you.

So that's what i've been up to for the past three weeks.

Hopefully the next couple will actually have a proper video on something.

For more infomation >> Vlog April 2018 - Failed experiments and work in progress on making alkali metals - Duration: 5:15.

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Upload notice - Duration: 0:40.

Hello. It's Marwin, the editor of Apple's YouTube

I'd like to give an emergency notice of uploading video today

The editor's midterm exam will start on Wednesday, April 25, 2018

Accordingly, the <Hypixel Challenge Four consecutive wins Unit 6> video will be uploaded on Saturday

and <Hypixel Challenge Win without a bed Unit 1> video will be uploaded on Sunday

My apologies to all you've been waiting for

For more infomation >> Upload notice - Duration: 0:40.

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THE THINGS NO ONE KNEW...| Personal story - Vlog 414 - Duration: 12:32.

What did you say?

I couldn't unlock my bicycle...

You can stop filming now.

Stop filming?

Why?

I used to like that but now no longer...

I'm going to show you some little things of my scooter. It's standing outside so we're just gonna take some pictures.

Iwill now try to show you how fast that scooter of mine pulls up!

Maybe it's not that visible, because I'm looking straight into the sun.

But we're gonna try it...

Let's go!

So as you could see it didn't really work out, to pull up really fast with the camera.

Because it was all becoming shaky and these FAT amateur images.

So another time you just come over and you can see it for yourself.

Yeah I'm just filming a small bit...

[INDUSTRIAL AREA]

*making weird sounds*

Have you heard about Scardekkel? (A friend who got injured falling fom a building)

What do you have there Bram?

Not sure, a piece of rubber...

Just purely cause we don't care...

Not to close to the gastank

*blond guy is my buddy Mark who you might know from the vlogs last summer*

*born to be wild* playing on the radio

AWESOME boy!

Always!

Now I shoot

Quick fingers...

You?

Do you know how to hold it? No... not like that.

At the car.

Was it nice?

AWESOME!

Three...Two..One... LET's GO!

For more infomation >> THE THINGS NO ONE KNEW...| Personal story - Vlog 414 - Duration: 12:32.

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PBS NewsHour full episode, April 24, 2018 - Duration: 56:12.

For more infomation >> PBS NewsHour full episode, April 24, 2018 - Duration: 56:12.

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Old MacDonald Had A Farm | Nursery Rhymes For Children - Duration: 1:12:20.

old MacDonald Had A Farm

For more infomation >> Old MacDonald Had A Farm | Nursery Rhymes For Children - Duration: 1:12:20.

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Свекольные зразы с черносливом. Вкусные котлеты из свеклы - Duration: 2:08.

For more infomation >> Свекольные зразы с черносливом. Вкусные котлеты из свеклы - Duration: 2:08.

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Dihh97-VHS (Oficial Video) - Duration: 2:05.

For more infomation >> Dihh97-VHS (Oficial Video) - Duration: 2:05.

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Машинки мультфильмы развивающие танковые баталии в игре Hills Of Steal Серия 2 - Duration: 7:56.

For more infomation >> Машинки мультфильмы развивающие танковые баталии в игре Hills Of Steal Серия 2 - Duration: 7:56.

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HOW TO DRAW Dress Apple Store Coloring Painting Pages for Kid 🔴 Fun Rainbow - Duration: 8:33.

HOW TO DRAW Dress

For more infomation >> HOW TO DRAW Dress Apple Store Coloring Painting Pages for Kid 🔴 Fun Rainbow - Duration: 8:33.

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L'eau au gingembre, la boisson la plus saine pour brûler toutes les graisses du ventre, du dos et de - Duration: 6:09.

For more infomation >> L'eau au gingembre, la boisson la plus saine pour brûler toutes les graisses du ventre, du dos et de - Duration: 6:09.

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APINK SPECIAL SINGLE ALBUM UNBOXING《기적 같은 이야기(MIRACLE)》| ITSJEMHERE - Duration: 7:10.

So today, I'd be speaking Taglish* (Tagalog+English)

Because... Just because.... HAHAHAH

Click CC to open the subtitles

She's actually beside me

But she doesn't want to show herself on the camera

I'll show you each of the pages/pictures

But for now, I'll only show my poster, what does the album look like

And briefly the pictures inside it

And also! The photocard that I'll get~

So! I'll open it now~~

So Ate* Ivy will hand me the poster that I'll show you guys (*Ate is like unni/noona)

So here's the album, it's so hot WTH (LOL)

So Ate Ivy will hand me the poster now

So I'll show it to you guys first

*oopsie~ SORRY SELF*

For Ate Ivy, she got Chorong

Just wait a minute///

This one's for Ate Ivy

Because there's 3 (posters) with her right now

So, this one...

Chorong~

Namjoo~

And of course, for me Hayoung

Cause she's my bias~~

Super THANK YOU Ate!!~~

I really can't get over (UH LOL)

She's really my bias (OKAY GURL WE GET IT STAHP)

OMG so luckehhhh

So infront is..

It's color green

There's actually 2 colors for the cover

The beige one, which is the one that Ate Ivy has

And for me I have the green one

Actually at first we were fighting on who will get the beige cover

But she liked it first so.. HAHAH

But the green one is okay too~

As I was saying, the one infront of the album says

"기적같은 이야기" which means MIRACLE

Ate Ivy: show them the beige one

So this is what the other version looks like

It's soooo pretty right?!?

Like The Bible~~ (cause of the color hehe)

So this is how both versions look like

They actually have the same pictures & setting

It's just the colors that are different

So yea again as I was saying, the one I have is the color green (IM ANNOYING SARREH HEHE)

In front of the album is Chorong, Naeun, and Eunji~~

And at the back is Hayoung, Bomi, and Namjoo~~

So I will now show you what's inside

But wait

Because my photocard might pop out (HAHA)

Ate please take out my photocard first please

Please don't show me ah

Please don't react HHAHAH

So she will hide/keep my photocard first ( for surprise )

Ate, please no (LOL @ ME HAHA)

Wait the photocard is missing XD

Okay wait she's looking for it...//

Okay so the album is here now again(& she kept my pc first)

Btw, i'm controlling my camera with my phone

We're in Burjuman* btw!! (Mall in Dubai)

Okay, so the photocard is gone. It's currently with Ate Ivy

Firstly, this is the certificate...//

Ate this is the donation certificate, right?

Cause part of the sales for the Miracle album

is a donation so...

this is like the certificate

that you'll get if you order this album

And, the title of the album

This one's a special album

that Apink does for their fans <3

So here's what's inside; Table Of Contents

So first, it's Chorong~

because it's by age LOL *sorry chorongie*

So it's Chorong, Bomi, Eunji, Naeun, Namjoo & Hayoung~~

So I'll show it to you more clearly guys

So I'll just show you guys each page once I get home~

So the CD is here, you'll just remove that thingy

I'll just open it later~

So now I'll show you guys the PC that I got

Ate Ivy will give it to me now~

Is this the side without the face? (facing me)

Ate Ivy: No...

This one?

Ate Ivy: Yes! That one~

So yea let's see who I got!~

I didn't get Hayoung ㅠㅠ

But it's okay ~ I love each of the members~

But yea Naeun is so pretty~~

So that you'll be notified everytime I have a video/new video~

For more infomation >> APINK SPECIAL SINGLE ALBUM UNBOXING《기적 같은 이야기(MIRACLE)》| ITSJEMHERE - Duration: 7:10.

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Why NRA Members Are Shooting Their Coolers - Duration: 6:37.

WHY ARE NRA MEMBERS BLOWING UP COOLERS?

LEAVE THE COOLERS ALONE.

REMEMBER BACK AFTER THE PARKLAND SHOOTING THERE WERE A LOT OF

COMPANIES THAT CUT TIES WITH THE NRA AND THE NRA WAS VERY UPSET

ABOUT THAT.

JUST HAVE THAT IN THE BACK OF YOUR MIND.

LAST FRIDAY, MEMBERS OF THE NRA GOT A LETTER FROM THE NRA

INSTITUTE FOR LEGISLATIVE ACTION AND THE FORMER NRA PRESIDENT

MARIAN P HAMMER.

THIS IS A REPORT FROM THE WASHINGTON POST ABOUT THAT

LETTER.

ACCORDING TO THEM:

IN THE WAKE OF THIS, PEOPLE WHO ARE NRA MEMBERS STARTED BLOWING

UP THEIR YETI COOLERS.

WE WILL SHOW YOU SOME OF THAT IN A SECOND.

THE DAMAGE HAD ALREADY BEEN DONE, BUT YETI RESPONDED.

OF COURSE SHE SAID IT THAT WAY.

BUT IN THE MEANTIME, THEY LOST THEIR MINDS AND PEOPLE

STARTED BLOWING UP.

HERE IS A VIDEO OF SOMEONE TAKING IT OUT ON THEIR YETI

COOLER AND REMEMBER, THEY HAVE NO REASON TO DO THIS NOW.

THEY FILL IT UP WITH TANNERITE AND IN ANOTHER ONE, SOME PEOPLE

DIDN'T HAVE COOLERS SO THIS GUY

TOOK IT OUT ON HIS YETI CUP.

TAKE A LOOK.

JOE WITH AEGIS TACTICAL.

THEY LOST THEIR MAN CARD.

THIS IS WHAT I THINK OF YETI.

GIVE ME A SECOND WHILE I LOAD IT UP.

THERE YOU HAVE IT.

THIS WAS OVER AT DISCOUNT.

OVER LOSING A DISCOUNT.

CAN YOU IMAGINE IF SOMEONE FREAKED OUT

THIS HARD OVER THEIR AAA DISCOUNT NO LONGER BEING VALID

OR A COUPON BEING EXPIRED?

I HAVE MIXED FEELINGS ABOUT THE STORY BECAUSE PART OF IT

IS SO GOOFY IT'S KIND OF FUN.

I ENJOY SEEING THAT COOLER BLOW UP, I HAVE TO BE HONEST

WITH YOU.

MAYBE IT IS THE KID IN ME.

BUT THEN I DON'T HAVE A GUN.

IT IS ONE THING WHEN YOU ARE PLAYING, IT IS ONE THING WHEN

IT IS ACTUAL BULLETS AND IT IS NOT A COOLER, BUT TO KIM'S

POINT, THINK ABOUT HOW TRIGGERED THEY GET, IF YOU WILL, THE

SMALLEST LITTLE THING.

WE ARE NOT GIVING YOU THE SAME DISCOUNT WE USE 2.

HOW DARE YOU.

YOU KNOW WHY?

THEY FILL ENTITLED.

THEY HAVE A SENSE OF ENTITLEMENT AND THEY ARE LIKE I DESERVE TO

HAVE EVERYTHING, INCLUDING ANY DISCOUNT THAT I LIKE AND IF

YOU TAKE AWAY MY DISCOUNT, YOU ARE TAKING AWAY MY FREEDOM.

NO WE ARE NOT.

WE ARE TAKING AWAY DISCOUNT BY THE WAY, YOU'VE ANOTHER ONE

ANYWAY.

BUT PUT THAT ASIDE.

EVEN IF THE STORY WERE ENORMOUSLY TRUE AND THEY HAD

BEEN DENIED THEIR 12% OFF.

THAT IS HOW CONSERVATIVES VIEW THINGS.

WHEN YOU SAY I DO NOT AGREE WITH KANYE WEST SUPPORTING CANDACE

OWENS OR DONALD TRUMP.

THERE LIKE YOU ARE TAKING HIS FREEDOM OF THOUGHT WAY.

NO I AM NOT, HE IS ALLOWED TO SAY ANY DUMB ASS THING HE WANTS.

I CAN ALSO SAY ANYTHING I ONE COUNTER HIS SPEECH.

NO, I AM ENTITLED TO BE THE ONLY ONE SPEAKING.

THESE THINGS COST $250-$300 SO I GUESS THEY ARE RICHER SOMETHING

OR PROBABLY, THEY ARE DOWN AND AFTER THEY BLOW IT OUT THEY ARE

LIKE THAT WAS $1100, WHAT DID I DO.

I SPENT THAT MONEY ALREADY.

WHY DID I DO THAT?

IT IS CRAZY.

IT IS CRAZY FOR US TO BE CALLED THE SNOWFLAKES.

I REALLY ENJOY, I GET WHAT YOU ARE SAYING BUT I REALLY

ENJOYED WATCHING EVERY SINGLE ONE OF THOSE VIDEOS.

WHILE THOSE WITH THE HIGHLIGHTS, THERE IS ONE WHERE A GUY TAKES

HIS CUP AND HE PUTS IN A VICE AND ONE OF THOSE TABLE VICES

THAT YOU HAVE TO SPEND AND IT TAKES HIM LIKE A FULL MINUTE

AND A HALF AND THE THING IS, THE YETI IS SO MALLEABLE

THAT NOTHING EVEN HAPPENS.

IT IS ACTUALLY A GREAT PRODUCT.

AND YOU ARE JUST FILMING THE NEED TO LOAD IT UP WITH 20

POUNDS OF TANNERITE TO MAKE IT EXPLODE.

THEY ARE ACCIDENTALLY DOING AN AD FOR YETI.

YOU ALREADY BOUGHT IT BECAUSE IT IS SO AWESOME AND YOU USED

THE DISCOUNT YOU STILL HAVE IT BUT I GET IT.

THERE'S SOMETHING ABOUT THAT MENTALITY.

I HAVE THE GUN AND I WANT TO USE IT.

I WILL USE IT FOR THIS.

SOME OF THEM, THEY LOOK LIKE THEY'RE HAVING AN AMAZING DAY.

I HAVE BEEN AT A GUN RANGE AND SHOT WEAPONS AND I TOLD THE

STORY IN THE POST GAME ABOUT AN AUTOMATIC WEAPON AND IT STARTED

SNOWING.

I AM LIKE WHY IS IT SNOWING INSIDE?

IT WAS BECAUSE I HAD ACCIDENTALLY SHOT THE CEILING.

SO IT WAS GOING ALL OVER THE PLACE.

THEY'RE LIKE TAKE THAT AWAY FROM HIM.

I GET THAT IT COULD BE FUN AND YOUR HOBBY AND LIKE A CHILD,

WHEN I SEE THE THINGS BEING SMASHED OR THINGS BEING PUT IN A

BLENDER OR A COOLER BLOWING UP, LITTLE PART OF ME GOES HOT LIKE

A LOT OF YOU DO BUT ON THE OTHER

HAND, WILL YOU OWN IS NOT HOBBY IT IS A KILLING MACHINE SEE HAVE

TO BE REALLY CAREFUL BUT ON THE OTHER HAND, A LOT OF PEOPLE, I

THINK THAT THEY THINK, I CANNOT WAIT TO USE THIS SO THAT IS

PART OF WHY THEY ARE BLOWING UP $1000

COOLER BECAUSE THEY CANNOT WAIT TO USE THE WEAPON.

IF IT WAS ALL FUN AND GAMES, NO BIG DEAL BUT WHEN YOU ACTUALLY

DO USE IN REAL LIFE, THAT IS

DISASTROUS AND POSSIBLY DEADLY SO THAT IS WHY WE ARE ASKING

YOU GUYS TO BE REALLY CAREFUL WITH YOUR HOBBY AND NOT FEEL SO

ENTITLED THAT YOU GET TO USE

IT WHENEVER AND HOWEVER YOU WANT.

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